Advances in Friedel-Crafts Acylation Reactions Catalytic and Green Processes

Advances in Friedel-Crafts Acylation Reactions

Samenvatting

Used in the production of a wide number of fine chemicals and pharmaceuticals, the Friedel-Crafts acylation reaction represents a synthetic process of great interest to organic chemists of academia and industry. Nearly 40 years since the last major treatise on the topic and reflecting the growing emphasis on green technology, Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes focuses on how to make this reaction more economically and environmentally friendly by using green acylating conditions, thus minimizing the formation of waste and decreasing production costs. Divided into four parts, the book explores stoichiometric acylations, catalytic homogeneous acylations, catalytic heterogeneous acylations, and phenol acylations. It is structured according to the role played by the catalyst in the activation of reagents as well as in the different modes of regioselectivity encountered in the acylation of arenes, aromatic ethers, and phenols. Incorporating examples of all acid-catalyzed Friedel-Crafts acylation reactions, the text considers classic Lewis and Broensted acid types along with more innovative and advanced multicomponent superacid catalysts. These range from rare earth triflates or triflimides and their combination with ionic liquids to metal-promoted zeolites and zeotypes, clays, polymetal oxides, sulfated zirconia, heteropoly acids, and Nafion. The book emphasizes the major industrial applications, providing a critical assessment of the differences, advantages, and disadvantages of homogeneous and heterogeneous catalysis. Helping readers to better understand the mechanism of the Friedel-Crafts acylation, the examples in the book substantiate the development of more effective catalysts and more selective processes achieved during the last few decades, enabling industry to embark on a safer and more efficient synthesis of aromatic ketones for the manufacture of a wide array of products.
Nog geen reviews

Productspecificaties

Inhoud

Taal
Engels
Bindwijze
Hardcover
Verschijningsdatum
november 2009
Aantal pagina's
216 pagina's
Illustraties
Nee

EAN

EAN
9781420067927

Overige kenmerken

Extra groot lettertype
Nee
NUR code
910
Subtitel
Catalytic and Green Processes

Je vindt dit artikel in

Categorieën
Studieboek of algemeen
Algemene boeken
Taal
Engels
Boek, ebook of luisterboek?
Boek
Bindwijze: Hardcover
241 99
Verwacht over 6 weken Tooltip
Verkoop door bol.com
In winkelwagen
  • Gratis verzending
  • 30 dagen bedenktijd en gratis retourneren
  • Ophalen bij een bol.com afhaalpunt mogelijk
  • Dag en nacht klantenservice